Recent developments in dark photocatalytic hydrogen production over smart catalysts
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Widespread application of solar-driven hydrogen production is hampered by two major challenges: the safety risks associated with high-pressure H2 storage and transport, and the intermittent nature of solar energy. Inspired by the natural spatial ...
MoreWidespread application of solar-driven hydrogen production is hampered by two major challenges: the safety risks associated with high-pressure H2 storage and transport, and the intermittent nature of solar energy. Inspired by the natural spatial and temporal separation of light and dark reactions in photosynthesis, the emerging strategy of dark photocatalysis aims to separate the collection and conversion of solar energy. In the past few years, encouraging progress has been made in the dark photocatalytic production of hydrogen. Therefore, we summarize the advances in this field over the past few years. This review first discusses various charge storage mechanisms in depth. Then, a comprehensive review of key material systems is conducted, covering carbon-nitrogen-based materials, metal–organic frameworks, polyoxometalate-based materials, two-dimensional layered materials, as well as heterojunction/interface engineering and the combination of semiconductors with polyoxometalates. Furthermore, the performance of photo-charging and dark hydrogen evolution is analyzed in detail. Finally, we look forward to the future development direction of this field. This review aims to offer valuable insights and guidance for the design of efficient and stable dark photocatalytic materials.
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Xiaoyu Dong, ... Yong Ding
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DOI: https://doi.org/10.70401/smd.2026.0032 - April 22, 2026
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This article belongs to the Special Issue Smart Porous Materials and Catalysis






